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Studies performed in animal models other than rats did not show any association between carbon black and lung tumors. Signs and Symptoms of Exposure : no data available Medical Conditions Generally Aggravated by Exposure : no data available Emergency and First Aid Procedures : SKIN- - - - - - - - -Wash away ink on skin EYE - - - - - - - - -Wash away water and consult a doctor promptly. INHALATION - - -Not applicable OTHERS- - - - - -No data available S H A R P MATERIAL SAFETY DATA SHEET (2/2) MSDS No. B-1021 Section 6. Physical Chemical Characteristics Boiling/Melting Point No data available Specific Gravity No data available Vapor Pressure No data available Solubility in Water Negligible Vapor Density No data available PH No data available Evaporation Rate No data available Viscosity No data available Appearance Thin film coated with ink Color Black Odor Slight wax odor Section 7. Fire and Explosion Data Flash Point (Method Used) :>150 ° C for ink Ignition Temperature : No data available Flammable Limits : (LEL); No data available (UEL); No data available Extinguishing Media : Water mist, Foam, Dry powder, CO2 gas, others Special Fire Fighting Procedure : No data available Unusual Fire and Explosion Hazard :None Sensitivity to Mechanical Impact : No hazardous effect by mechanical impact Sensitivity to Static Charge : Not appicable Section 8. Reactivity Data Stability :Stable Incompatibility (Materials to Avoid) :None Hazardous Decomposition :None Hazardous Polymerization : Will not occur Section 9. Precautions for Safe Handling and Use Personal Protection Information (Respiratory, Eye Protection and Protective Glove) : Hnad protection : Desireble in some cases Engineering Control / Ventilation : No data available Work / Hygienic Practice :None Steps to be taken in case of Spill or Leak : If inadvertently released, rewind ribbon. Waste Disposal Method : Disposal in accordance with local, state and federal regulations. Section 10. Regulatory Information NFPA Rating (U.S.A.) : No information WHMIS Legislation (Canada) : Not controlled Transport Information : No information UN No. : Not applicable Section 11. Other Information References : IARC(1996) Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Humans, Vol. 65, Printing Process and Printing Inks, Carbon Black and Some Nitro Compounds, Lyon, pp-149-261 H. Muhle, B. Bellmann, O. Creutzenberg, C. Dasenbrock, H. Ernst, R. Kilpper, J. C. Mackenzie, P. Morrow, U. Mohr, S.Takenaka, and R. Mermelstein (1991) Pulmonary Response to Toner upon Chronic Inhalation Exposure in Rats. Fundamental and Applied Toxicology 17, pp. 280-299 S H A R P Date Revised: . Date Issued :Dec. 22, 1998 MATERIAL SAFETY DATA SHEET (1/2) MSDS No. B-1006 Section 1. Product Identification Product Code : FO-3CR Imaging Film Section 2. Supplier's Name and Address Sharp Corporation 22-22 Nagaike-cho, Abeno-ku, Osaka, Japan Local suppliers are listed below. Please contact the nearest supplier for additional information. (Country) (Name and Telephone Number) U.S.A. Sharp Document Network System of America Telephone number for information: 1-800-237-4277 Emergency telephone number : 1-800-255-3924 Canada Sharp Electronics of Canada Ltd. Telephone number for information: 905-890-2100 Emergency telephone number : 1-800-424-9300 United Kingdom Sharp Electronics (U.K.) Ltd. Telephone number for information: 01923-474013 Section 3. Ingredients Ingredients CAS No. Proportion OSHA PEL ACGIH TLV Other Limits Polyethylene terephthalate 25038-59-9 51.0% --- Carbon Black 1333-86-4 8.5% 3.5 mg/m3 3.5 mg/m3 - Ethylene-vinyl acetate copolymer 24937-78-8 3.1% --- Ester wax 8015-86-9 5.6% --- Parraffin Wax 8002-74-2 12.5% -2 mg/m3(fume) - Microcrystalline wax 63231-60-7 15.2% --- Modified wax 8016-60-2 1.3% --- Polyester resin 27923-68-8 1.3% --- Others - 1.5% --- Section 4. Hazardous Identification (Emergency Overview) This product is ink film for thermal transfer facsimile. “Ink film” is a thin film coated with ink. It is no special hazard under normal use condition. Section 5.Health Hazard Data Route(s) of Entry : Inhalation? Skin? Ingestion? Not applicable Not applicable Possible but very unusual Health Hazards :The ingredients are not listed in ACGIH(1986) and OSHA(1989) except carbon black and paraffin wax. Carcinogenicity : In 1996 the IARC reevaluated carbon black as a Groupe 2B carcinogen (possible human carcinogen). This classification is given to chemicals for which there is inadequate human evidence, but sufficient animal evidence on which to base an opinion of carcinogenicity. The classification is based upon the development of lung tumors in rats receiving chronic inhalation exposures to free carbon black at levels that induce particle overload of the lung. Studies performed in animal models other than rats did not show any association between carbon black and lung tumors. Signs and Symptoms of Exposure : not applicable Medical Conditions Generally Aggravated by Exposure : not ap...